rod03801: "Stuff on Desktop, etc."

Well, what's shown on your desktop is just the content of the folder %HOMEPATH%\Desktop. You can just copy it from, for example,

C:\Documents and Settings\rod1\Desktop

to

C:\Documents and Settings\rod2\Desktop

You can do that with your documents from "My Documents" as well. And for some applications this will work if you copy what's in %APPDATA%

C:\Documents and Settings\rod1\Application Data