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Undertaker.: How would single elimination tournaments work as a team tournament? - that is how would the match up work since the current format of the tournament is that it would be easy enough to make the first round be one team against another team, but the next round, the winner of each round moves forward so it would turn into where players on the same team would play themselves.
As for being able to let the captain switch around the order of players. An interesting idea, but for myself if I'm not too good of a player, and if the captain decided to place me against the top player as a "sacrafice" lose so the team can keep their top player to play someone else, I would be a little upset. That is at least now how it is setup, if I'm the 4th best of the team, I know I'll go against the 4th best on the other team - I may still be over matched, but at least it would give me more of a chance then going against their top player.